The Hedley Chief showing is situated on the west side of Winkler Creek, 3.5 kilometres northwest of Hedley.
This area on the south side of Stemwinder Mountain is underlain by argillite, siltstone and limestone of the Upper Triassic Stemwinder Mountain Formation (Nicola Group). These sediments are intruded by diorite and gabbro sills and dykes of the Early Jurassic Hedley Intrusions.
Some stripping carried out by Hedley Chief Mines near the creek in 1936 exposed some pyrite and pyrrhotite, with traces of chalcopyrite and arsenopyrite, in "green silicate rocks" (skarn?).